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South African Journal of Chemistry

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Instructions to authors..../ Instructions aux auteurs....

Publication Policy: Original work in all branches of chemistry is published in the South African Journal of Chemistry. Contributions in English may take the form of papers or short communications, and critical reviews may occasionally be published. All manuscripts are assessed by referees, and may be returned to the authors if extensive revision is required or if the style or presentation does not conform to Journal practice. It is understood that copyright for all published material is vested in the South African Chemical Institute and that authors bear sole responsibility for the factual accuracy of their publications. The use of electronic technology at all stages in the publication process leads to rapid publication times, and wide dissemination of the research presented.

A Paper is a comprehensive contribution to the subject, and includes all essential experimental information and a critical discussion of results. Introductory material and background discussion should be terse and relevant. Although brevity is encouraged, a long but cohesive paper is more acceptable than fragmented accounts on a single theme. A Short Communication is a concise account (ca. 1500 words) of novel and significant results of which urgent publication is warranted. Short communications will be processed as expeditiously as possible. A Review is an authoritative and critical account of recent and current research in a specialized field, to which the author has made notable contributions. Prospective authors are requested to submit to the Secretariat a suggested topic and a brief outline of the scope of the review before writing it. On submitting material for publication, authors are encouraged to supply the names and e-mail addresses of two or three potential referees. The editors reserve the right to approach these nominated referees, or not, at their discretion. Authors submitting work for publication are required to complete and sign an exclusive copyright transfer form, without which publication may not proceed. Copyright transfer forms may be printed, completed, signed and either posted or faxed to the Secretariat at the address given below.

Lay-out of Manuscripts: Manuscripts should be prepared using one of the standard word-processing packages, e.g. Microsoft Word or Word Perfect. The preferred font is Arial 12 point which also contains greek letters under the subset "Basic Greek" (otherwise use the font Symbol), with a line spacing of 1.5. Indent all paragraphs, and avoid breaking a word at the end of a line, except where a hyphen occurs. The first page should commence with the name and complete address of the author to whom correspondence is to be sent. The Title, which should be concise but sufficiently informative for information retrieval purposes, should be followed by the authors' names (one given name, initials and surname). The complete address(es) should be typed below the appropriate author(s).

The text of the manuscript should be preceded by an Abstract of no more than 200 words in English. The abstract should not contain information which is meaningless without referring to the text; thus avoid equation and formula numbers unless qualified by an adequate description. Do not refer to illustrations, tables and literature. For short communications the abstract should be limited to one or two short sentences.

A paper may be organized under main headings such as Introduction, Results, Discussion (or Results and Discussion), and Experimental. A limited number of side-headings may be employed if they aid comprehension. In short communications the text should not be interrupted by headings; but essential experimental information should be given under the heading Experimental.

Content of Manuscripts: Authors should follow IUPAC rules for nomenclature and the International System of Units (SI) as far as possible. Familiar abbreviations may be used, but should be defined once if any doubt exists. Experimental data for organic and inorganic compounds should be presented in a consistent manner; the preferred sequence for reporting the new data is: m.p., [a ]D, l max, e , n max, m/z (Found: C, ; H, ; N,. Calc. for CwHxNyOz : C, ; H, ; N, %). Superfluous data, e.g =2E m/z and n max details, which are not structurally significant, should be omitted. Novel preparations of known compounds should be accompanied by a literature reference and significant comparative data, e.g. lit.,_ m.p., [a]D. Standard preparations of known compounds are unnecessary, and repetitive descriptions of similar procedures should be avoided. In the latter cases one typical description will suffice, and may be accompanied by tables of analytical and spectral data.

Tables should be numbered consecutively in arabic numerals (e.g. Table 1) and should bear a short, yet adequate caption. Footnotes to tables should be designated by lower-case letters which appear as superscripts to appropriate entries. Tables should be in a readable form not exceeding A4 size in portrait format. Column headings should be organized such that they represent a physical quantity divided by its unit, e.g. T/K, so that the entries in the columns are dimensionless. Columns of integral numbers should be right-justified, and floating-point numbers should be aligned according to their decimal points. Tables should be prepared using the Microsoft Word table function, rather than using tabulations. They should be positioned within the body of the text, at the nearest convenient location to their first mention in the text.

Equations should be numbered consecutively using parenthesized arabic numerals flush with the right-hand margin. When numbering, make no distinction between chemical and mathematical equations. Equations should commence at the left-hand margin, signs should be spaced, and no more than 50 characters (including spaces) should occupy each line in the manuscript. In mathematical equations, use the solidus (/) to minimize space requirements. Wherever possible, complicated superscripts and subscripts should also be typed in a single line with the aid of a solidus. Exponential expressions should be presented as exp(...). Equations generated using other software (e.g. ChemDraw or Microsoft Equation) than the word-processor, should not be embedded in the text, but should be submitted as JPG (or GIF, PSP, BMP) files and as original files. The position of the equation should be clearly indicated in the text.

References should be numbered consecutively in order of appearance in the text, as unparenthesised superscripts to the right of any punctuation, and are listed at the end of the paper. Journal references are given by initials and surnames of all authors, journal, year, volume, first page; and book references by initials and surnames of all authors, title (initials and surnames of all editors followed by ed. or eds.), volume, edition, publisher, city or cities, country, date, page(s). Titles of journals are abbreviated according to Chemical Abstracts practice (see 'Bibliographic Guide for Editors and Authors'. American Chemical Society, Washington, 1974). Authors should avoid using footnotes, and the use of reference managers is discouraged.

Illustrations should be submitted on separate A4 sheets. There are no restrictions on the use of colour for articles appearing in The South African Journal of Chemistry; indeed authors are encouraged to make full use of colour graphics in order to enhance the presentation of their work. Graphics files should be prepared at a maximum width and height of 500 pixels, with white space being kept to a minimum, while retaining an opaque background. JPG, GIF, ChemDraw and ChemWindows files are preferred. Authors should use graphics computer packages, ensuring that lines have uniform thickness and that lettering is of a size which will be clearly legible after reduction. Freehand or typewritten drawings or lettering are not acceptable. One set of original illustrations, or glossy photoprints, and three sets of copies should accompany each submission. All original illustrations must be fully identified on the back. Labels of the axes of graphs, like Table column headings, should represent a physical quantity divided by its unit, e.g. ln(k/dm_ mol-_ s-_), so that the quantities on the axes are dimensionless. Figures should be numbered consecutively using arabic numerals (e.g. Figure 1), and descriptive captions should be included in the text at the appropriate positions. Illustrations should not exceed A4 size and should be submitted as separate JPG (or GIF, PSP, BMP) files.

Three-dimensional Images of, for example, results from molecular modelling or molecular orbital calculations may be displayed as 3D images, which allow readers to rotate, zoom in, etc. to inspect the figures more closely. These figures may be viewed using the Chime™ plug-in (

Structural formulae should be drawn with the aid of standard computer packages, such as ChemWindows or ChemDraw, and individually designated by unparenthesised boldface arabic numerals corresponding to those in the text; roman numerals are not acceptable. Authors who use ChemDraw must use the built-in ACS style when preparing structural formulae. Authors who use other drawing packages must adjust the settings so that they are as close as possible to the following specifications: bond length: 0.508 cm (14.4 point); double bond spacing: 18% of bond length; bold width: 0.071 cm (2 point); line width: 0.021 cm (0.6 point); hash spacing: 0.088 cm (2.5 point); chain angle: 120º; font: Arial 10 point. When several structural formulae are depicted, they should be grouped in logical blocks and not scattered throughout the text. Numbering should be consecutive if possible, and formulae should not be repeated if used in a later lay-out; the number will suffice. Blocks of numbered structural formulae do not usually require further designation, but their preferred position in the text should be indicated. Reaction and mechanistic sequences may be numbered and referred to as schemes if this facilitates discussion in the text. A descriptive caption is preferred when the scheme is numbered. For submission of structural formulae and schemes the same instructions apply as for the submission of illustrations. For editing purposes they should be sent as original files in addition.

Spectra: Many software packages allow spectra, chromatograms, etc. to be saved in JCAMP-DX format. The file specifications for some of these packages are available free from the IUPAC Working Party on Spectroscopic Data Standards (JCAMP-DX) website. Plots in JCAMP-DX format may then be displayed using the Chime™ plug-in, and expanded and manipulated on screen. Providing JCAMP-DX files allows readers to save published spectra for direct comparison with their own spectra.

Crystallographic data: Papers containing crystallographic data are assessed in terms of their chemical significance. However, sufficient data should be included to enable other workers to reproduce and extend the calculations. The presentation of crystal data should conform to recommendations of the Commission on Crystallography of the IUCr (Acta Crystallogr., 1967, 22, 445). Authors should submit for refereeing purposes and subsequent deposition (see Supplementary Material) all supplementary crystallographic data as a Crystallographic Information File (CIF), which should include anisotropic vibrational parameters and structure factor tables: these tables should not be numbered. Significant derived data, such as those bond lengths, bond angles and torsion angles, with their estimated standard deviations, which are necessary for the discussion, should be tabulated for publication. Full details of the refinement should be included. Authors presenting molecular coordinates from crystallographic or modelling studies in their submitted articles should use Brookhaven Protein Databank (PDB), MDLI Molfile or xyz formats. While coordinates provided by most crystallographers normally come in SHELX format, conversion of SHELX to PDB format may be easily accomplished using SHELX93, Chem3D or Babel.

Supplementary Material: In certain cases, detailed compilations of data or calculations may be considered by the authors, or by the editors and referees, to be of limited interest to readers. Authors may submit or be advised to submit such information as supplementary material. At the time of publication this will be deposited in the CSIR Reference Library in Pretoria, and copies will be made available to interested readers at a nominal charge.

Archiving and Compressing Files: For ease of handling, text and graphic files may be archived and compressed into one single file. Utilities such as WinZip and Stufflt will archive and compress authors' files. Other programs such as TAR will archive files, which can then be compressed using a program such as gzip. Recommended file types include ZIP, ARJ, LZH, TAR, Z, GZ, TAZ, TGZ, UUencode, BinHex and MIME.

Manuscripts for publication should be submitted to: The Secretary, The South African Chemical Institute, P.O. Box 407, Wits, 2050, South Africa.

Manuscripts must be submitted in triplicate on A4 paper, using 1.5-spaced typescript with adequate margins. Table headings with the tables and figure captions should be included. All illustrations, figures, equations etc. must be submitted separately. A machine readable form of the manuscript in the correct publication format should be available and sent via email or on diskette by mail on request. All files to be submitted in machine readable form must be thoroughly checked for viruses before submission.

Acceptance of an article is confirmed when the article is passed for editing. A diskette containing the files corresponding exactly to the text must be submitted with the final (accepted) version of the manuscript. Submission of the files by email is encouraged. The editors reserve the right to make further changes to bring manuscripts up to the expected standards and in conformity with the in-house style.

The author will be notified when proofs of an article are available for checking. Authors are requested to return any proof changes to Sabinet within 48 hours of notification that the proofs are ready for checking. Articles published in The South African Journal of Chemistry may not be published elsewhere without the written permission of the South African Chemical Institute. Submission of article files is regarded as an undertaking that the same material is not being considered for publication in another journal.